Energy Impacts

Catalyzing the Sustainable Decomposition of PFAS Forever Chemicals

Daniel Morton — Sat, 21 Dec 2024 00:30:44 +0000

Catalyzing the Sustainable Decomposition of PFAS Forever Chemicals Daniel Morton Fri, 12/20/2024 - 17:30

Daniel Morton

RASEI Fellow Niels Damrauer is part of a collaborative team that have developed a new light-driven C-F activation reaction, one that has the potential to help dismantle PFAS ‘forever chemicals’

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Highlight in The Conversation

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Perfluoroalkyl and polyfluoroalkyl substances, or PFAS, are synthetic compounds that have found widespread use in consumer products and industrial applications. Their water and grease resistant properties have been part of their attraction in their applications, but these are also the reason that they are now found practically everywhere in the environment, they are very difficult to decompose.

While many chemicals will decompose relatively quickly, studies have shown that PFAS are expected to stick around for up to 1000 years. While this durability is great in something like firefighting foams or non-stick cookware, it is not great when these compounds get into the environment.

This new article, published in Nature in November of 2024, describes the work of a collaborative team of theoretical and experimental chemists, who have developed a new photochemical reaction that could hold promise of speeding up the decomposition of PFAS. A recent highlight of this work, written by the graduate student and postdoctoral fellows who did the research, appeared in The Conversation.

Using a photocatalyst, that absorbs light to speed up a reaction, the researchers were able to ‘activate’ one of the carbon-fluorine bonds, one of the strongest bonds in organic chemistry. The photocatalyst absorbs light, transfers electrons to the fluorine containing molecules, which then breaks down the sturdy carbon-fluorine bond.

While this doesn’t decompose the whole molecule, it is essentially like finding a chink in the armor, it opens the door to degradation of the PFAS to harmless smaller molecules.

This study demonstrated this process on a small scale, and the researchers are looking at how to optimize this reaction so it is more robust and can be done on larger scales. This work is part of a National Science Foundation funded Center for Chemical Innovation called SuPRCat, a research community that will be looking at this challenge, among others.

If it is possible to break down these forever chemicals, it will help prevent these environmental pollutants being in our soil, rivers, and drinking water. Excited to see the next steps from the team!

December 2024

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Permafrost instability negates the positive impact of warming temperatures on boreal radial growth

Daniel Morton — Tue, 03 Dec 2024 03:24:57 +0000

Permafrost instability negates the positive impact of warming temperatures on boreal radial growth Daniel Morton Mon, 12/02/2024 - 20:24

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2024, 121, 50, e2411721121

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The importance of integrating energy justice into chemistry graduate student research and the associated pathways and barriers

Daniel Morton — Tue, 26 Nov 2024 03:11:21 +0000

The importance of integrating energy justice into chemistry graduate student research and the associated pathways and barriers Daniel Morton Mon, 11/25/2024 - 20:11

NATURE CHEMISTRY, 2024, https://doi.org/10.1038/s41557-024-01681-z

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Photocatalytic C–F bond activation in small molecules and polyfluoroalkyl substances

Daniel Morton — Wed, 20 Nov 2024 18:50:57 +0000

Photocatalytic C–F bond activation in small molecules and polyfluoroalkyl substances Daniel Morton Wed, 11/20/2024 - 11:50

NATURE, 2024

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RASEI Fellows receive 2024-2025 Deloitte and CIC Research Awards

Daniel Morton — Mon, 11 Nov 2024 21:11:59 +0000

RASEI Fellows receive 2024-2025 Deloitte and CIC Research Awards Daniel Morton Mon, 11/11/2024 - 14:11

Daniel Morton

The Climate Innovation Collaboratory (CIC) was launched as a collaborative venture between CU ��«��Ƶ and Deloitte, with the goal of translating cutting-edge climate research and data into meaningful climate solutions for businesses, organization, government agencies and communities.

This year three RASEI Fellows were recipients of awards to develop long-term engagements with Deloitte and expand access to critical climate data analytics, research and technology. These projects explore how the renewable energy grid can be built out to offer clean solutions for AI data centers and greater adoption of electric vehicles.

RASEI Fellow Bri-Mathias Hodge is the principal investigator for a project titled “Interconnection Planning for Large Data Centers”. The goal is to develop a system planning tool to automate the initial processes needed for utilities to identify generation expansion, network reinforcement, and asset upgrades to meet the demands of new data centers. This work will help utilities, grid operators, and data center operators to deal with the expansion in the number and energy usage of data centers at the state, regional, and international levels. With the rise of AI, seen as the industrial revolution of the 21^st century, better understanding of how and where to place the data centers that are the engines driving this transformation will be critical.

RASEI Fellow Kyri Baker is the principal investigator for a project titled “Viability of long- and short-duration energy storage for AI Data Centers: Carbon, Cost, and Reliability”. This project combines the benefits of short and long duration energy storage to increase uptime, improve renewable energy utilization, and lower payback periods for AI data centers. By developing an optimization framework for data centers energy storage that leverages price and renewable energy forecasts to co-optimize cost, carbon, and resilience. Creation of a tool that optimizes data energy storage would have significant relevance to commercial and government clients seeking to lower data center consumption.

RASEI Fellow Stephanie Weber is the principal investigator for a project titled “EV Infrastructure and local economic spillovers”. This project seeks to understand both how the construction of public electric vehicle charging infrastructure affects the surrounding areas as well as the tradeoffs associated with prioritizing equity in public charging locations. This will help inform state and national governments in the deployment of EV charging stations, to help incentivize EV adoption, and better understand the non-monetary impact of building EV chargers.

11/11/2024

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Study of Photodegradation of Organic Solar Cells Under Brazilian Climate Conditions

Daniel Morton — Thu, 07 Nov 2024 03:27:21 +0000

Study of Photodegradation of Organic Solar Cells Under Brazilian Climate Conditions Daniel Morton Wed, 11/06/2024 - 20:27

ENERGIES, 2024, 17, 22, 5533

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Renewable Energy: Where are the Jobs? Panel Discussion

Daniel Morton — Tue, 22 Oct 2024 21:36:58 +0000

Renewable Energy: Where are the Jobs? Panel Discussion Daniel Morton Tue, 10/22/2024 - 15:36

Daniel Morton

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On October 22, 2024, RASEI partnered with Colorado WRISE to host a panel discussion exploring careers in the renewable energy sectors.

The Colorado Women of Renewable Industries and Sustainable Energy, or Colorado WRISE, is a local chapter of the nationwide organization that seeks to change our energy future through the collective power of community. The panel consisted of seven leaders from across a range of renewable sectors, from national lab, through utilities and non-profits, to power systems.

The panelists introduced themselves with a short biography and answered questions on everything from how they made their way into careers in the renewable sector, to the future of careers in this growing space.

Thank you to all the panelists and organizers!

10/22/2024

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POSE Fall 2024 Kickoff Workshop

Daniel Morton — Mon, 07 Oct 2024 22:43:24 +0000

POSE Fall 2024 Kickoff Workshop Daniel Morton Mon, 10/07/2024 - 16:43

Daniel Morton

In early October of 2024, RASEI hosted the kickoff workshop for POSE, a new community being brought together to address some of the most critical challenges we face to do with plastics and polymers.

Polymer Solutions for the Environment, or POSE, seeks to establish a Center that will bring together expertise around the development of a circular polymer economy.

Plastics and polymers are critical materials in the modern age, forming the building blocks of everything from electronics to packaging, but this versatility comes with a cost, namely the waste and infiltration of the environment by microplastics.

This workshop brought together thought leaders in the polymer sector, from a cross section of academic, national lab and industrial organizations. The goal was to explore how best the POSE community can build a program that complements existing efforts in the field to drive the science and policy forward.

Three areas of focus were discussed, including the development of a circular polymer economy, the development of polymers that are needed for a just clean energy transition, and the integration of the science and technology research with policy, economics and social sciences.

It was a great meeting with more than 60 participants who came together to discuss ideas, present their research and approaches, and help shape the goals and directions of this nascent community.

10/07/2024

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Growing Agrivoltaics

Daniel Morton — Mon, 30 Sep 2024 17:30:01 +0000

Growing Agrivoltaics Daniel Morton Mon, 09/30/2024 - 11:30

JOURNAL OF PHOTONICS FOR ENERGY, 2024, 14, 3, 030101

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The climate-energy nexus: a critical review of power grid components, extreme weather, and adaptation measures

Daniel Morton — Thu, 12 Sep 2024 17:21:10 +0000

The climate-energy nexus: a critical review of power grid components, extreme weather, and adaptation measures Daniel Morton Thu, 09/12/2024 - 11:21

ENVIRONMENTAL RESEARCH: INFRASTRUCTURE AND SUSTAINABILITY, 2024, 032002

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